Polymer adhesion in heat‐treated nonwovens

Polymer adhesion and sintering in compound nonwovens was studied. Nonwovens containing a mixture of binding bi‐component (BICO) fibers embedded in a fibrous matrix were heated to melt the outer shell of BICO fibers and interlock the matrix to create stiff load‐bearing surfaces. It was found that stiffness depends on heat‐treatment regimes. In low‐temperature regimes, BICO fibers melt, but do not fully flow and encase the surrounding filler matrix. At sufficiently high temperatures, the shells of BICO fibers melt and flow which results in encasing the neighboring filler fibers. This results in an abrupt increase in the nonwoven stiffness which is independent of heat‐treatment temperature. At significantly high temperatures, the filler matrix fibers sinter to each other leading to a further increase in stiffness. The experiments were conducted with co‐polymers frequently used in the shells of BICO to demonstrate the interlocking mechanism characteristic of these compound nonwovens. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46165.