| 金属／溶液界面氧化还原反应的量化处理初探 |
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| 引用本文： | 姜兆华 刘宏. 金属／溶液界面氧化还原反应的量化处理初探[J]. 哈尔滨工业大学学报, 1992, 24(2): 71-77 |
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| 作者姓名： | 姜兆华 刘宏 |
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| 作者单位： | 哈尔滨工业大学应用化学系，哈尔滨工业大学应用化学系 讲师 |
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| 摘 要： | 对金属腐蚀体系中界面反应进行综合量子化学处理还是一个探索性的工作,本文用简化势垒模型的方法,把问题适当简化后进行量化计算,给出了微观参数与界面反应速率的半定量关系式,并同电化学测量结果相比较,证明了该计算所给出的半定量判断与实验事实相等。
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| 关 键 词： | 金属 量子化学 界面 氧化还原 腐蚀 |
A Tentative Quantum-Chemical Approach to Redox Reactions in Metal-Solution Interface |
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| Jiang Zhaohua Liu Hong. A Tentative Quantum-Chemical Approach to Redox Reactions in Metal-Solution Interface[J]. Journal of Harbin Institute of Technology, 1992, 24(2): 71-77 |
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| Authors: | Jiang Zhaohua Liu Hong |
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| Affiliation: | Jiang Zhaohua Liu Hong |
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| Abstract: | It is a tentative work to conduct reasearch on redox reations in n-metal corrosion system by means of quantum-chemical method. In this paper, the problem is solved by simplifying a potential barrier model.The semiquantitative formulas concernc microcosmic parameters with rate of the radox reactions are given and the result obtained from semiquantitative calculation is as same as that of electrochemical measure. |
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| Keywords: | Fatty acid homologue interfacial barrier potential transtion probability |
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