| Abstract: | Transfer rates of copper and hydrogen ion through a cation exchange membrane were measured experimentally for the systems of Cu/H-SO4 and Cu/H-NO3. Transfer rates of anions in the membrane were also measured, and they were negligible compared to those of the cations. Cupric ion and hydrogen ion transfer in a ratio of 1:2 and in opposite directions. The self-diffusion coefficient of cupric ion in the membrane is obtained from the transfer rate of copper in high concentrations of sulfuric or nitric acid solutions using the equilibria data obtained in our previous work. The coefficient of the hydrogen ion is similarly obtained. |
