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一种新的芒硝制碱法实验室研究
引用本文:王天贵, ,李佐虎. 一种新的芒硝制碱法实验室研究[J]. 中国化学工程学报, 2004, 12(3): 433-438
作者姓名:王天贵     李佐虎
作者单位:StateKeyLaboratoryofBiochemicalEngineering,InstituteofProcessEngineering,ChineseAcademyofSciences,Beijing100080,China
基金项目:国家自然科学基金,国家高技术研究发展计划(863计划)
摘    要:The purpose of this work is to find a new way for utilizing the rich sodium sulfate resource to produce soda ash. A novel process is proposed which uses aqueous dichromate solution as working medium through decomposition of calcium carbonate in aqueous sodium dichromate, complex decomposition of aqueous sodium sulfate and calcium chromate, regeneration of sodium dichromate and production of sodium bicarbonate from carbonation of aqueous sodium chromate solution, processing and utilization of byproduct calcium sulfate, and production of sodium carbonate from sodium bicarbonate. The process has the features of less corrosion and pollution and low energy consumption.

关 键 词:硫酸钠 碳酸钙 碳酸钠 苏打 重铬酸钠 硫酸钙 碳酸盐
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Preliminary Study on a Novel Process for Manufacturing Soda Ash from Sodium Sulfate
WANG Tiangui,LI Zuohu. Preliminary Study on a Novel Process for Manufacturing Soda Ash from Sodium Sulfate[J]. Chinese Journal of Chemical Engineering, 2004, 12(3): 433-438
Authors:WANG Tiangui  LI Zuohu
Affiliation:State Key Laboratory of Biochemical Engineering,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100080,China;State Key Laboratory of Biochemical Engineering,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100080,China
Abstract:The purpose of this work is to find a new way for utilizing the rich sodium sulfate resource to produce soda ash.A novel process is proposed which uses aqueous dichromate solution as working medium through decomposition of calcium carbonate in aqueous sodium dichromate,complex decomposition of aqueous sodium sulfate and calcium chromate,regeneration of sodium dichromate and production of sodium bicarbonate from carbonation of aqueous sodium chromate solution,processing and utilization of byproduct calcium sulfate,and production of sodium carbonate from sodium bicarbonate.The process has the features of less corrosion and pollution and low energy consumption.
Keywords:sodium sulfate  calcium carbonate  sodium carbonate  soda ash  sodium dichromate  calcium sulfate
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