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Differential pulse effects of solid electrolyte interface formation for improving performance on high-power lithium ion battery
Authors:Fu-Ming Wang  Hsin-Yi WangMeng-Han Yu  Yi-Ju HsiaoYing Tsai
Affiliation:a Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei, Taiwan
b Sustainable Energy Center, National Taiwan University of Science and Technology, Taipei, Taiwan
c Department of Chemical Engineering, National Tsing Hua University, Hsinchu, Taiwan
Abstract:Solid electrolyte interface (SEI) formation is a key that utilizes to protect the structure of graphite anode and enhances the redox stability of lithium-ion batteries before entering the market. The effect of SEI formation applies a differential pulse (DP) and constant current (CC) charging on charge-discharge performance and cycling behavior into brand new commercial lithium ion batteries is investigated. The morphologies and electrochemical properties on the anode surface are also inspected by employing SEM and EDS. The electrochemical impedance spectra of the anode electrode in both charging protocols shows that the interfacial resistance on graphite anodes whose SEI layer formed by DP charging is smaller than that of CC charging. Moreover, the cycle life result shows that the DP charging SEI formation is more helpful in increasing the long-term stability and maintaining the capacity of batteries even under high power rate charge-discharge cycling. The DP charging method can provide a SEI layer with ameliorated properties to improve the performance of lithium ion batteries.
Keywords:Solid electrolyte interface   Lithium ion battery   Pulse   Formation   Cycle
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