Polarized Raman spectra of doubly oriented poly(vinyl alcohol) |
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Authors: | Kohji Tashiro Masamichi Kobayashi Hiroyuki Tadokoro |
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Affiliation: | (1) Department of Polymer Science, Faculty of Science, Osaka University, Toyonaka, 560 Osaka, Japan |
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Abstract: | Polarized Raman spectra of doubly oriented samples of atactic poly(vinyl alcohol) have been measured. The great usefulness of such polarized spectra has been clarified for the vibrational analysis. The normal coordinate treatments of syndiotactic and isotactic poly(vinyl alcohol) chain models gave good agreement between the observed and calculated frequencies. |
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