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The properties of equimolar copolycarbonates of bisphenol A with bisphenol S and 1,4-bis(hydroxymethyl)cyclohexane
Authors:M Yenigul  IW Parsons  JN Hay  RN Haward
Affiliation:Department of Chemistry, University of Birmingham, Birmingham, B15 2TT, UK
Abstract:Ranges of both alternating and random 1:1 copolycarbonates of Bisphenol-A (2,2-bis(4-hydroxyphenyl)propane) and Bisphenol-S (4,4′-dihydroxydiphenyl sulphone) and of Bisphenol-A and 1,4-dimethanoylcyclohexane have been synthesized in order to test the hypothesis that, other things being equal, a more random structured polymer should exhibit superior thermal ageing characteristics. Studies on these materials' mechanical and thermal properties establish that within each pair they are extremely similar and hence the original hypothesis is disproved.
Keywords:Copolymers  alternating  random  polycarbonate  polysulphone  physical ageing  mechanical properties  Bisphenol-A  Bisphenol-S  dimethanoylcyclohexane
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