Magnesium alkyl reduced titanium (IV) chloride based polymerization catalysts: materials rich in magnesium chloride

Reduction of TiCl₄ with organomagnesiums either in the presence of preformed MgCl₂, or concurrently with the formation of MgCl₂ from chlorocarbons, yields materials which are active catalysts for the polymerization of propene and ethene. Transformation of these materials to a violet allotrope by heating with TiCl₄ gives materials much more active for propene polymerization, albeit stereoregulation is still not good. interestingly, these transformed materials show little advantage for ethene polymerization except at high temperatures. Use of a Lewis base does not give high stereoregulation with propene; although some advantage is gained activity is greatly diminished by this.