Drag reduction and mechanical degradation in polymer solutions in flow |
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Authors: | Witold Brostow |
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Affiliation: | Department of Materials Engineering, Drexel University, Philadelphia, PA 19104, USA |
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Abstract: | A list of conclusions from experimental studies of drag reduction (DR) and mechanucal degradation in flow (MDF) is made. A statistical-mechanical model of chain conformations developed by the author9 is used, and its consequences for DR and MDF established. Experimental findings are explained in terms of the model, including those considered to be puzzling and contrary to expectations. A relation between the extent of mechanical degradation and flow time is derived. The equation obtained for relative drag reduction in function of time reproduces perfectly the experimental data for polystyrene+toluene solutions reported by Hunston and Zakin12. Some predictions from the present model have yet to be tested experimentally. |
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Keywords: | Polymer solutions macromolecular conformations chain scission drag reduction mechanical degradation turbulent liquid flow |
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