Modeling of the enantioselective hydrogenation of 1-phenyl-1,2-propanedione over Pt/Al2O3 catalyst |
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| Authors: | Esa Toukoniitty, P ivi M ki-Arvela, Johan W rn ,Tapio Salmi |
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| Affiliation: | Laboratory of Industrial Chemistry, Process Chemistry Group, Åbo Akademi, FIN-20500 Turku/Åbo, Finland |
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| Abstract: | A kinetic model was developed for the enantioselective hydrogenation of 1-phenyl-1,2-propanedione based on parallel racemic and enantioselective routes in the presence of cinchonidine. The Langmuir–Hinshelwood type of competitive adsorption approach was used in the model, which was combined with a batch reactor model. The proposed model could sufficiently describe the observed kinetic results. |
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| Keywords: | Enantioselective hydrogenation 1-Phenyl-1,2-propanedione Pt/Al2O3 catalyst |
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