Curing Characteristics and Mechanical and Morphological Properties of Styrene Butadiene Rubber/Virgin Acrylonitrile-Butadiene Rubber (SBR/vNBR) and Styrene Butadiene Rubber/Recycled Acrylonitrile-Butadiene Rubber (SBR/rNBR) Blends

Curing characteristics and mechanical and morphological properties of styrene butadiene rubber/virgin acrylonitrile-butadiene rubber (SBR/vNBR) and styrene butadiene rubber/recycled acrylonitrile-butadiene rubber (SBR/rNBR) were investigated. Results indicated that the curing characteristics, such as scorch time, t₂, and cure time, t₉₀, of SBR/vNBR and SBR/rNBR blends decreased with increasing vNBR and rNBR content. At similar blend ratios, particularly up to 15 phr, SBR/rNBR blends exhibited higher t₂ and t₉₀ compared with SBR/vNBR blends. Minimum torque (ML) and maximum torque (MH) of SBR/vNBR blends significantly increased with increasing vNBR content. For SBR/rNBR blends, ML increased with increasing rNBR content, but MH exhibited the opposite trend. Tensile strength, elongation at break (E_b), resilience, and fatigue decreased with increasing virgin and recycled NBR content in both blends. Up to 15 phr, the tensile strength, E_b and fatigue life (Kc) of SBR/rNBR blends were higher than in SBR/vNBR blends. The M100 (stress at 100% elongation), hardness, and cross-linking density of both blends also showed an increasing trend with increasing vNBR and rNBR content. The scanning electron microscopy study indicates that rNBR exhibited a weak rNBR-SBR matrix interaction particularly when more than 15 phr of rNBR was used, thus decreasing the mechanical properties of SBR/rNBR blends.