Synthesis and properties of Np(VI) and Pu(VI) monophthalates

Neptunium(VI) and plutonium(VI) monophthalates were prepared and characterized. The complexes AnO₂ (COO)₂C₆H₄ 2H₂O were isolated from cold solutions, and AnO₂ (COO)₂C₆H₄ 1.33H₂O, from hot solutions. NpO₂ (COO)₂C₆H₄ b. 2H₂O and PuO₂ (COO)₂C₆H₄ 2H₂O crystalize in the triclinic and monoclinic systems, respectively. The complexes AnO₂(COO)₂C₆H₄ 1.33H₂O are isostructural and crystallize in the rhombohedral system. The thermal behavior of these complexes was studied. Their IR and electronic absorption spectra were recorded. The properties of these complexes were compared to those of known U(VI) monophthalates.Translated from Radiokhimiya, Vol. 46, No. 5, 2004, pp. 389–395.Original Russian Text Copyright © 2004 by Krot, Bessonov, Grigorev, Charushnikova, Makarenkov.