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高分子表面活性剂的合成
引用本文:富洁琪,张建敏,冯梦婷,黄树津,任强,胡建波. 高分子表面活性剂的合成[J]. 广州化工, 2011, 39(22): 33-34,36
作者姓名:富洁琪  张建敏  冯梦婷  黄树津  任强  胡建波
作者单位:温州大学化学与材料工程学院,浙江温州,325035
基金项目:浙江省大学生科技创新项目资助(No:2010R424010)
摘    要:以丙烯酸、丙烯酰胺和丙烯酸丁酯为单体,采用瞬时聚合法合成了高分子表面活性剂。表面活性研究表明,制备的高分子表面活性剂有良好的表面活性,表面张力可低至42 mN/m。红外光谱表明,产物没有发生交联,黏度法测定产物的分子量为2×104~4×104。

关 键 词:高分子表面活性剂  瞬时聚合  表面张力  分子量

The Synthesis of Polymeric Surfactants
FU Jie-qi,ZHANG Jian-min,FENG Meng-ting,HUANG Shu-jin,REN Qiang,HU Jian-bo. The Synthesis of Polymeric Surfactants[J]. GuangZhou Chemical Industry and Technology, 2011, 39(22): 33-34,36
Authors:FU Jie-qi  ZHANG Jian-min  FENG Meng-ting  HUANG Shu-jin  REN Qiang  HU Jian-bo
Affiliation:FU Jie-qi,ZHANG Jian-min,FENG Meng-ting,HUANG Shu-jin,REN Qiang,HU Jian-bo(College of Chemistry and Materials Engineering,Wenzhou University,Zhejiang Wenzhou 325035,China)
Abstract:Polymeric surfactants were prepared by instant polymerization,using acrylic acid,acrylamide and butyl acrylate as monomers.Properties and structures were characterized by FT-IR and viscosimetry.The results showed that there was no crosslink structure in polymeric surfactants and the polymeric surfactants had good surface activities,with the lowest surface tension of 42 mN/m and molecular weight of 2×104~4×104.
Keywords:polymeric surfactants  instant polymerization  surface tension  molecular weight  
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