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RAFT聚合制备嵌段共聚物的研究进展
引用本文:宫希杰,谷崇,叶妮雅,李晓芳,张梁,雷良才. RAFT聚合制备嵌段共聚物的研究进展[J]. 当代化工, 2014, 0(10): 2078-2083
作者姓名:宫希杰  谷崇  叶妮雅  李晓芳  张梁  雷良才
作者单位:辽宁石油化工大学化学与材料科学学院高分子材料与工程系,辽宁抚顺,113001
摘    要:RAFT聚合具有反应条件温和,对单体纯度和环境的要求相对较低等优势,近年来通过RAFT方法制备嵌段共聚物已经受到了高分子化学领域研究者的广泛关注。简要介绍了近10年来通过RAFT方法制备嵌段共聚物所常用的RAFT试剂和单体的研究进展,主要介绍了近10年来线型两嵌段、三嵌段共聚物和星型嵌段共聚物的RAFT聚合及应用。

关 键 词:RAFT  嵌段共聚物  合成  应用

ResearchProgress in preparation of Block Copolymers via RAFT
GONG Xi-jie,GU Cong,YE Ni-ya,LI Xiao-fang,ZHANG Liang,LEI Liang-cai. ResearchProgress in preparation of Block Copolymers via RAFT[J]. Contemporary Chemical Industry, 2014, 0(10): 2078-2083
Authors:GONG Xi-jie  GU Cong  YE Ni-ya  LI Xiao-fang  ZHANG Liang  LEI Liang-cai
Affiliation:GONG Xi-jie;GU Cong;YE Ni-ya;LI Xiao-fang;ZHANG Liang;LEI Liang-cai;College of Chemistry and Materials Science,Liaoning Shihua University;
Abstract:RAFT polymerization hasmanyadvantages, such asmild reaction conditions, relatively low requirements forpurity of the monomer,andso on. In recent years, preparation of block copolymers by RAFT has been paid widespread attention in the field of polymer chemistry. Inthis article, RAFT agents and monomers were introduced. The recent research progress in preparation of block copolymers by RAFT was discussed, and RAFT polymerization and application of linear diblock, triblock and star copolymerswere introduced.
Keywords:RAFT  Block copolymers  Synthesis  Application
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