Ionic liquids as diathermic fluids for solar trough collectors’ technology: A corrosion study |
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| Authors: | Ilaria Perissi Ugo Bardi Stefano Caporali Alessio Fossati Alessandro Lavacchi |
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| Affiliation: | aDipartimento di Chimica, Università di Firenze, Via della Lastruccia 3, 50019 Sesto Fiorentino (FI), Italy;bConsorzio Interuniversitario Nazionale di Scienza e Tecnologia dei Materiali (INSTM), Unità di Ricerca di Firenze, 50147 Firenze, Italy |
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| Abstract: | The AISI 304 and AISI 1018 steels (frequently used in solar collectors’ plants) in contact with four different ionic liquids (ILs) suitable as diathermic fluids, were studied. Immersion tests were performed at 220 °C (the working temperature in such plants) for 10 days. The corrosion morphologies of the steels were investigated by scanning electron microscopy coupled with energy dispersive X-ray (EDX) microanalysis and the content of metals in the solution were detected via ICP-OES. The tests showed that the most performing IL is the ethyl-dimethyl-propyl-ammonium-bis(trifluoromethylsulphonyl)imide. The corrosion properties of the two alloys in contact with such IL were investigated by means of Tafel plots and resistance polarization at room temperature in open-to-air vessels. |
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| Keywords: | Solar collectors Ionic liquids Steels’ corrosion Tafel plots |
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