Electrochemical determination of trihalomethanes in water by means of stripping analysis

A protocol has been developed and evaluated for the determination of trihalomethanes (THMs) at the submicromolar concentration level in water. This method is based on a three-step stripping analysis that utilizes a single electrochemical cell and that entails (a) direct electrochemical reduction of a trihalomethane at a silver cathode to form halide ions in an aqueous sample containing tetraethylammonium benzoate, (b) capture of the released halide ions as a silver halide film on the surface of a silver gauze anode, and (c) cathodic reduction and quantitation of the silver halide film by means of differential pulse voltammetry. Using this procedure, we have determined THMs individually; bromoform and chloroform have been successfully quantitated in 30 min and with a detection limit of 3.0 μg L(-1) (12 nM) and 6.0 μg L(-1) (50 nM), respectively. In addition, we have employed our methodology to determine the total trihalomethane (TTHM) content in a prepared water sample at a level commensurate with the maximum allowable annual average of 80 μg L(-1) mandated by the United States Environmental Protection Agency. We have compared our TTHM results to those obtained by an independent testing laboratory.