Enhanced mechanical properties of graphene/natural rubber nanocomposites at low content

Graphene/natural rubber (GE/NR) nanocomposites were prepared by a modified latex mixing method combined with in situ chemical reduction. It was found that the GE nanosheets are well dispersed and have strong interfacial interaction with NR. Thus, adding a low content of GE can remarkably increase the tensile strength and the initial tensile modulus of NR. With incorporation of as low as 0.5 phr of GE, a 48% increase in the tensile strength and an 80% increase in the initial tensile modulus are achieved without sacrificing the ultimate strain. But further increasing the GE loading degrades the tensile strength and the ultimate strain. Dynamic mechanical measurement indicates that the storage modulus of the nanocomposites is greatly enhanced with addition of GE, while the loss tangent peak is depressed due to the reduced mobility of the rubber molecules. The reinforcement effect of GE on NR is interpreted as a change in the strain induced crystallization and network structure of the nanocomposites, based on the analysis of Mooney ? Rivlin plots and the tube model.© 2013 Society of Chemical Industry