Influence of acrylic impact modifier on plasticized polylactide blown films |
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Authors: | Huiliang Zhang Hongyu Liang Junjia Bian Yanping Hao Lijing Han Xuemei Wang Guibao Zhang Sanrong Liu Lisong Dong |
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Affiliation: | 1. Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, , Changchun, 130022 China;2. Changchun University of Technology, , Changchun, 130022 China;3. Graduate School, Chinese Academy of Sciences, , Beijing, 100080 China |
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Abstract: | Polylactide (PLA) was first plasticized with polydiethylene glycol adipate (PDEGA). Then the plasticized PLA was further blended with acrylic impact modifier (ACR) using a twin‐screw extruder. Finally, the extruded samples were blown using the blown thin film technique. Both PDEGA and ACR significantly affected the physical properties of the films. The results indicated that elongation at break and the tear strength of the films were significantly improved. The cavitation and large plastic deformation observed in films subjected to the tear test were the important energy‐dissipation process, which led to a torn PLA film. Moreover, the PLA/PDEGA/ACR blown films had excellent optical properties. ACR could act as a tear resistance modifier for PLA blown films. These findings contribute new knowledge to the additives area and give important implications for designing and manufacturing polymer packaging materials. © 2013 Society of Chemical Industry |
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Keywords: | polylactide acrylic impact modifier blown film plasticizer mechanical properties |
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