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Novel Heterogenized Palladium(II) Complexes Anchored to Polymer Matrices Functionalized with Bis(diphenylphosphino)methane Moieties |
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| Authors: | Federica Benvenuti Carlo Carlini Mario Marchionna Renata Patrini Anna Maria Raspolli Galletti Glauco Sbrana |
| Affiliation: | (1) Dipartimento di Chimica e Chimica Industriale, University of Pisa, via Risorgimento 35, I-56126 Pisa, Italy;(2) SNAMPROGETTI S.p.A., via F. Maritano 26, I-20097 San Donato Milanese &lpar, MI), Italy |
| Abstract: | The synthesis and structural characterization of a novel bidentate ligand such as bis(diphenylphosphino) methane bound to a cross-linked styrene/divinylbenzene resin and to linear poly(styrene) are reported. Moreover, the anchoring of palladium acetate to the above polymeric ligands is described and the structure of the heterogenized palladium(II) complexes obtained is proposed. |
| Keywords: | Styrene/divinylbenzene resins phosphinated styrene polymers polymer-bound palladium complexes bis(diphenylphosphino)methane ligand |
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