Investigation of electrochromic properties of poly(3,5-bis(4-methoxyphenyl)dithieno[3,2-b;2′,3′-d]thiophene) |
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Authors: | Onur Sahin Ipek Osken Turan Ozturk |
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Affiliation: | 1. Department of Chemistry, Faculty of Science, Istanbul Technical University, Maslak, Istanbul 34469, Turkey;2. TUBITAK UME, Chemistry Group Laboratories, PO Box 54, 41470, Gebze-Kocaeli, Turkey |
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Abstract: | Electropolymerization of 3,5-bis(4-methoxyphenyl)dithieno3,2-b;2′,3′-d]thiophene BMPhDTT, having strong electron-donating methoxy groups, was performed, utilizing potentiodynamic method. The homopolymer was characterized by cyclic voltammetry (CV), Fourier transform infrared (FTIR) and UV–vis spectroscopy. Spectroelectrochemical and electrochromic properties of the homopolymer film were investigated and a PBMPhDTT/PEDOT device was constructed to understand its characteristics in detail. It was revealed that the potential range of 0.0–2.0 V is suitable for operating the device between yellow and blue colors. It indicated a good open circuit memory and stability. |
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