Effect of polyaniline–montmorillonite nanocomposite powders addition on corrosion performance of epoxy coatings on Al 5000 |
| |
| Authors: | MG Hosseini M Jafari R Najjar |
| |
| Affiliation: | 1. Department of Physical Chemistry, Electrochemistry Research Laboratory, University of Tabriz, Tabriz, Iran;2. Department of Organic Chemistry, Polymer Research Laboratory, University of Tabriz, Tabriz, Iran;1. Department of Electrical, Electronic and Systems Engineering, Universiti Kebangsaan Malaysia (UKM), Bangi 43600, Selangor, Malaysia;2. Department of Industrial Engineering, Science and Research Branch, Islamic Azad University, Kerman, Iran;1. Department of Electrical, Electronic and Systems Engineering, Universiti Kebangsaan Malaysia, Malaysia;2. Department of Engineering, Kerman Branch, Islamic Azad University, Kerman, Iran;1. Department of Electrical, Electronic and Systems Engineering, Universiti Kebangsaan Malaysia (UKM), Malaysia;2. Nano Abzar Pars Co., 168, 2nd Kazemi St., Hemmat Sq., Shokouhieh Industrial Zone, Qom, Iran;3. Department of Engineering, Kerman Branch, Islamic Azad University, Kerman, Iran;1. Department of Electrical Engineering, Science and Research Branch, Islamic Azad University, Kerman, Iran;2. Department of Electrical Engineering, National University of Malaysia, Bangi 43600, Selangor, Malaysia;3. Department of Civil and Structural Engineering, National University of Malaysia, Bangi 43600, Selangor, Malaysia;4. Department of Civil Engineering, Anar Branch, Islamic Azad University, Anar, Iran;1. Department of Electrical, Electronic and Systems Engineering, UniversitiKebangsaan Malaysia (UKM), Malaysia;2. Department of Engineering, Kerman Branch, Islamic Azad University, Kerman, Iran |
| |
| Abstract: | A series of polyaniline (PANI)/montmorillonite (MMT) nanocomposite materials has been successfully prepared by in-situ emulsion polymerization in the presence of inorganic nanolayers of clay with camphorsulfonic acid (CSA) and ammonium peroxydisulfate (APS) as surfactant and initiator, respectively. The nanocomposite materials were characterized by Fourier Transformation Infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and scanning electron microscopy (SEM). Epoxy resin was used as a binder for the nanocomposites in order to obtain a thick and uniform coating. In order to understand the effect of MMT and PANI on the corrosion inhibition performance of the epoxy coatings in 3.5% saline solution at 65 °C, the epoxy (E), epoxy blend with polyaniline (EP), epoxy blend with polyaniline and MMT (EPM) coatings were investigated by electrochemical impedance spectroscopy (EIS). The results showed that EPM coatings with 5% clay on pretreated aluminum by anodizing were much superior in corrosion protection, with respect to the other samples. Incorporation of PACN nanocomposites inside the epoxy significantly increases the resistance of the coating in comparison to the other coatings in 3.5% saline solution at 65 °C. These phenomena can be attributed to specific morphology of the nanocomposite. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
