New powellite type oxides in Ca–R–Nb–Mo–O system (R = Y, La, Nd, Sm or Bi)—Their synthesis, structure and dielectric properties

New complex oxides having powellite (CaMoO₄) type structure in the Ca–R–Nb–Mo–O system (R = Y, La, Nd, Sm or Bi) were prepared employing the method of solid state reaction between the component oxides at high temperature (1000–1100 °C). The new compounds, CaRNbMoO₈ (R = Y, La, Nd, Sm, Bi) are colorless and electrical insulators. The dielectric constants (K at 1 MHz) of these compounds are in the range 14–33 and K shows very little variation in the temperature range 30–100 °C. Their temperature coefficient of dielectric constant (TCK) is negative, which varies from − 21 to − 220 ppm/°C.