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NR/TPI并用胶半有效硫化体系的研究
引用本文:王付胜,李旭东,王波,赵永仙,刘争男,黄宝琛.NR/TPI并用胶半有效硫化体系的研究[J].特种橡胶制品,2005,26(5):9-14,22.
作者姓名:王付胜  李旭东  王波  赵永仙  刘争男  黄宝琛
作者单位:青岛科技大学橡塑材料与工程教育部重点实验室,山东,青岛,266042
摘    要:考察了促进剂NS用量、硫黄用量和硫载体DTDM对NR/反式-1,4-聚异戊二烯(TPI)并用胶性能的影响.结果表明,在半有效硫化体系中,硫黄用量1.2~1.4份,促进剂NS用量1.4~1.6份时,NR/TPI(80/20)并用胶可以获得良好的综合性能.NR/TPI中使用DTDM后,硫化速度虽略有降低,但胶料焦烧时间延长,加工安全性提高,硫化胶物理机械性能、疲劳性能、滚动阻力以及耐老化性能均得到改善,这与DTDM在NR中的应用相似.

关 键 词:天然橡胶  反式-1  4-聚异戊二烯  硫化体系
文章编号:1005-4030(2005)05-0009-06
收稿时间:2004-12-27
修稿时间:2004-12-27

Study on Semi-EV System of NR/Trans-1,4-polyisoprene Blends
WANG Fu-sheng,LI Xu-dong,WANG Bo,ZHAO Yong-xian,LIU Zheng-nan,HUANG Bao-chen.Study on Semi-EV System of NR/Trans-1,4-polyisoprene Blends[J].Special Purpose Rubber Products,2005,26(5):9-14,22.
Authors:WANG Fu-sheng  LI Xu-dong  WANG Bo  ZHAO Yong-xian  LIU Zheng-nan  HUANG Bao-chen
Affiliation:Qingdao University of Science and Technology,Qingdao 266042,China
Abstract:The effects of the levels of sulfur and accelerator NS and DTDM on the properties of NR/TPI blends were investigated.The results showed that the good comprehensive properties of NR/TPI(80/20)blends were obtained when the semi-efficient vulcanization system with 1.2~1.4 phr sulfur and 1.4~1.6 phr accelerator NS was used.It was showed that the cure rate was reduced little,but the longer scorch time was attained,when DTDM was added to NR/TPI blends,and the mechanical properties,fatigue resistance,rolling resistance and thermal aging properties of vulcanizates were improved obviously.
Keywords:DTDM
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