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响应曲面法优化氧化铜渣浮选提铜工艺
引用本文:王安琪,王永良,叶礼平,鲁永刚,钱鹏,叶树峰.响应曲面法优化氧化铜渣浮选提铜工艺[J].化工学报,2018,69(7):3018-3028.
作者姓名:王安琪  王永良  叶礼平  鲁永刚  钱鹏  叶树峰
作者单位:1.中国科学院过程工程研究所多相复杂系统国家重点实验室, 北京 100190;2.中国科学院大学化学与化工学院, 北京 100049;3.江西新金叶实业有限公司, 江西 上饶 334114
基金项目:十三五国家重点研发计划项目(2017YFC0703200)。
摘    要:江西某炼铜炉渣含铜量高,具有较高的经济价值。由于该铜渣中铜矿物以氧化矿为主,且硫化矿表面被氧化,直接浮选铜回收率低、经济效益差。通过添加活化剂,活化氧化铜矿物,并利用响应曲面中心复合设计原理对浮选工艺条件进行优化,研究氧化钙、硫化钠、Z-200对浮选效果的响应。结果表明,Z-200用量是影响精矿品位和回收率的主要因素,且各响应因素间存在交互效应,在CaO用量为25 g/t,Na2S用量为500 g/t,Z-200用量为100 g/t的最优条件下,闭路试验获得精矿平均品位12%,精矿铜回收率为86.57%,采用该浮选优化工艺能获得较好的回收效果。

关 键 词:氧化铜  铜渣  活化  浮选  响应曲面法  数学模拟  
收稿时间:2017-12-06
修稿时间:2018-04-24

Optimization of recycling copper from copper oxide smelting slag by response surface methodology
WANG Anqi,WANG Yongliang,YE Liping,LU Yonggang,QIAN Peng,YE Shufeng.Optimization of recycling copper from copper oxide smelting slag by response surface methodology[J].Journal of Chemical Industry and Engineering(China),2018,69(7):3018-3028.
Authors:WANG Anqi  WANG Yongliang  YE Liping  LU Yonggang  QIAN Peng  YE Shufeng
Affiliation:1.State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;2.School of Chemistry and Chemical Engineering of University of Chinese Academy of Sciences, Beijing 100049, China;3.Jiangxi Xinjinye Industry Co., Ltd., Shangrao 334114, Jiangxi, China
Abstract:The copper smelting slag with high copper content from Jiangxi has high economic value. Due to the copper mineral in the copper slag is mainly oxidized ore and the surface of the sulfide ore is oxidized, the copper recovery rate is low and the economic efficiency is poor. In this study, the copper oxide is activated by the addition of activator. To optimize the process conditions, the reaction surface methodology and the center composite design principle are used to investigate the response of the calcium oxide, sodium sulfide and Z-200 collector. The results show that the amount of Z-200 is the main factor affecting the grade and recovery rate of concentrate, and there are interaction effects among the response factors. The flotation index of close circuit test was achieved under the optimum conditions:CaO of 25 g/t, Na2S of 500 g/t and Z-200 of 100 g/t. The average grade of Cu in flotation concentrate is 12%, and the copper recovery is 86.57%, which proved that the flotation optimized process can obtain better recovery effect.
Keywords:copper oxide  copper slag  activation  flotation  response surface methodology  mathematical modeling  
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