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褶皱石墨烯球对润滑油摩擦性能的影响
引用本文:张姗姗,赵建国,张进,邢宝岩,钱瑞,曹宇,杨晓峰,王宝俊.褶皱石墨烯球对润滑油摩擦性能的影响[J].化工学报,2018,69(10):4479-4485.
作者姓名:张姗姗  赵建国  张进  邢宝岩  钱瑞  曹宇  杨晓峰  王宝俊
作者单位:1. 太原理工大学煤科学与技术教育部和山西省重点实验室, 山西 太原 030024; 2. 山西大同大学炭材料研究所, 山西 大同 037009
基金项目:山西省石墨烯产业化应用技术协同创新中心项目;山西省石墨烯功能材料工程技术研究中心项目(201705D141034);山西省人才专项项目(优秀人才科技创新)(201705D211010);山西省重点研发计划(工业项目)(201703D121037-2);大同市应用基础研究项目(2017123)。
摘    要:利用带有长链烷烃的硬脂酸和油酸对球状石墨烯进行表面修饰,得到亲油性褶皱石墨烯球(MCGB),采用FTIR、SEM等方法对其结构和形貌进行表征;研究了MCGB不同比例添加量在基础油中的分散性能和摩擦性能,并探讨MCGB在润滑油中的润滑机理。结果表明:基础油中添加少量MCGB可以明显改善其抗磨减摩效果,其中添加量为0.010%时效果最佳,但添加过量其减摩性能会失效。

关 键 词:褶皱石墨烯球  基础油  长链烷基  摩擦性能  
收稿时间:2018-04-23
修稿时间:2018-07-11

Effect of crumpled graphene balls on friction performance of base oil
ZHANG Shanshan,ZHAO Jianguo,ZHANG Jin,XING Baoyan,QIAN Rui,CAO Yu,YANG Xiaofeng,WANG Baojun.Effect of crumpled graphene balls on friction performance of base oil[J].Journal of Chemical Industry and Engineering(China),2018,69(10):4479-4485.
Authors:ZHANG Shanshan  ZHAO Jianguo  ZHANG Jin  XING Baoyan  QIAN Rui  CAO Yu  YANG Xiaofeng  WANG Baojun
Affiliation:1. Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China; 2. Institute of Carbon Materials, Shanxi Datong University, Datong 037009, Shanxi, China
Abstract:Modified crumpled graphene balls (MCGB) with hydrophobicity were prepared through a reflux reaction with stearic and oleic acids. The structure and morphology were characterized by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The dispersion properties and friction properties of different mass content of MCGB in base oil were studied, and the anti-friction mechanism of MCGB in lubricating oil was discussed. The results showed that the base oil with adding a small amount of MCGB can obviously improve the anti-wear and anti-friction capacity, and the optimal content of MCGB was 0.010%. But the anti-friction performance would be ineffective when adding excessive MCGB.
Keywords:crumpled graphene balls  base oil  long chain alkyl  friction performance  
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