| 聚芳醚醚酮酮腈的合成与表征 |
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| 引用本文： | 徐曲,余义开,蔡明中,宋才生.聚芳醚醚酮酮腈的合成与表征[J].石油化工,2003,32(11):999-1002. |
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| 作者姓名： | 徐曲 余义开 蔡明中 宋才生 |
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| 作者单位： | 江西师范大学,化学学院,江西,南昌,330027 |
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| 基金项目： | 国家“863”计划项目(863-715-15-01-04)，江西省自然科学基金资助项目(020312)。 |
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| 摘 要： | 在KOH和K2CO3存在下,通过2,6-二氯苯甲腈与苯酚在N-甲基吡咯烷酮中的缩合反应,合成了一种新单体2,6-二苯氧基苯甲腈。在无水AlCl3及NMP存在下,将其与对苯二甲酰氯、间苯二甲酰氯在1,2-二氯乙烷中进行低温溶液缩聚,合成了聚芳醚醚酮酮腈(PCEEKK)。用IR、DSC、TG、WAXD等方法对其结构和性能进行了表征。结果表明,聚合物的玻璃化转变温度(Tg)为160～180℃,比聚芳醚酮酮(Tg=156℃)要高,失重温度(Td)为471-495℃;DSC和WAXD的分析表明,PCEEKK为非晶态聚合物。
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| 关 键 词： | 聚芳醚醚酮酮腈 二苯氧基苯甲腈 低温溶液缩聚 对苯二甲酰氯 间苯二甲酰氯 |
| 文章编号： | 1000-8144(2003)11-0999-04 |
| 修稿时间： | 2003年5月26日 |
Synthesis and Characterization of Aromatic Polycyano Ether Ether Ketone Ketone |
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| XU Qu,YU Yi - kai,CAI Ming - zhong,SONG Cai - sheng.Synthesis and Characterization of Aromatic Polycyano Ether Ether Ketone Ketone[J].Petrochemical Technology,2003,32(11):999-1002. |
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| Authors: | XU Qu YU Yi - kai CAI Ming - zhong SONG Cai - sheng |
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| Abstract: | A novel monomer 2,6 - diphenoxybenzonitrile (DPOBN) was prepared by condensation of 2,6 -dichlorobenzonitrile with phenol in N - methyl pyrrolidone (NMP)in the presence of KOH and K2CO3. An aromatic polycyano ether ether ketone ketone (PCEEKK) was synthesized by low temperature solution polycondensation of 2,6 - diphenoxybenzonitrile with terephthaloyl dichloride (TPC), isophthaloyl dichloride (IPC) in 1,2 - dichloroethane and in presence of AlC13 and NMP. IR,DSC,TG,WAXD techniques were used to characterize the polymers. Tg of prepared polymers were in range of 160 - 180 ℃ , higher than that of PEKK ( Tg = 156 ℃ ), Td of prepared polymers were in range of 485 - 495 ℃ . Polymers were noncrystalline. Polymers had excellent heat - resistance and good solubility in dimethyl - formamide, NMP and dimethyl sulphoxide. |
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| Keywords: | aromaic polycyano ether ether ketone ketone diphenoxybenzonitrile low temperature solution polycondensation terephthaloyl dichloride isophthaloyl dichloride |
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