| 核壳型聚丙烯酸酯乳液硬挺整理剂的合成与应用研究 |
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| 引用本文： | 岳公星,鞠福生,刘俊娜,常冬艳,刘俊龙. 核壳型聚丙烯酸酯乳液硬挺整理剂的合成与应用研究[J]. 江苏印染, 2013, 0(11): 42-45 |
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| 作者姓名： | 岳公星 鞠福生 刘俊娜 常冬艳 刘俊龙 |
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| 作者单位： | [1]大连工业大学纺织与材料工程学院,辽宁大连116034 [2]大连新元化工技术有限公司,辽宁大连116035 [3]大连工业大学服装学院,辽宁大连116034 |
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| 摘 要： | 以苯乙烯（ST）、甲基丙烯酸甲酯（MMA）、丙烯酸丁酯（BA）为主要原料，采用乳液聚合法，合成了性能稳定的核壳型聚丙烯酸酯硬挺剂。通过红外光谱仪（FT—IR）验证了聚合物的分子结构。对涤纶织物进行硬挺整理，可有效满足实际要求的整理工艺为：硬挺剂600g／L，200℃焙烘1．5min。结果表明，合成的硬挺剂具有优良的硬挺效果，整理后的织物高温不泛黄或泛黄不明显，厚重感明显增加且耐水洗性良好。
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| 关 键 词： | 硬挺整理 硬挺剂 丙烯酸酯 乳液聚合 涤纶织物 泛黄 |
Synthesis and application of core-shell polyacrylate emulsion stiffening agent |
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| YUE Gong-xing,JU Fu-sheng,LIU Jun-na,CHANG Dong-yan,LIU Jun-long. Synthesis and application of core-shell polyacrylate emulsion stiffening agent[J]. , 2013, 0(11): 42-45 |
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| Authors: | YUE Gong-xing JU Fu-sheng LIU Jun-na CHANG Dong-yan LIU Jun-long |
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| Affiliation: | 1. School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, China; 2. Dalian Xinyuan Chemical Company Limited, Dalian 116035, China; 3. School of Clothing, Dalian Polytechnic University, Dalian 116034, China ) |
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| Abstract: | Core-shell polyacrylate stiffening agent was synthesized via emulsion polymerization using styrene（ST）, methyl methacrylate（MMA）, butyl acrylics（BA） as main monomers. Molecular structure of the polymer was verified by Fourier transform infrared spectroscopy（FT-IR）. The finishing process for polyester fabric was defined as follows： stiffing agent 600 g/L, cured at 200 ~C for 1.5 min. The treated fabric met the actual requirements effectively. The results showed that synthetic stiffening agent presented excellent stiffness. The finished fabric performed non-yellowing or unconspicuous yellowing at high temperature, significant thickness increase and good washability. |
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| Keywords: | stiffing finishing stiffing agent acrylics emulsion polymerization polyester fabric yellowing |
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