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Contribution to carrier densities of the oxygen vacancy in a low-resistivity tin-doped indium oxide film by the hot-cathode plasma sputtering method
Authors:Akihiko Kono  Tatsuzo Nagai
Affiliation:a Faculty of Engineering, Kyushu Kyoritsu University, Kitakyushu, 807-8585, Japan
b Research Laboratory for Integrated Technological Systems, Kanazawa Institute of Technology, Hakusan, 924-0838, Japan
c Kyushu Kyoritsu University Research Center, Kitakyushu, 807-8585, Japan
Abstract:In order to clarify the contribution to carrier density by oxygen vacancies in tin-doped indium oxide (ITO) films prepared on glass substrates by the hot-cathode plasma sputtering method, we have investigated the effect of annealing on the electrical properties of an ITO film with a resistivity of 1.0 × 10− 4 Ω cm. A drastic decrease in carrier density from 2.0 × 1021 to 0.88 × 1021 cm− 3 was found with gradual increase in the Hall mobility from 29 to 35 cm2 V− 1 s− 1 for repeated annealing cycles, when the ITO film was exposed for one hour to 400 °C oxygen gas at atmospheric pressure. The results indicate that the contribution of oxygen vacancies to carrier density was ca. 1.12 × 1021 cm− 3 for the ITO film with an overall carrier density of 2.0 × 1021 cm− 3.
Keywords:Thin film   Indium tin Oxide (ITO) film   Transparent conducting oxide (TCO) film   Sputtering
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