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A novel non-catalytic approach for fabrication of bamboo-like carbon nanotubes
Authors:Fei Wang
Affiliation:State Key Laboratory of Coordination Chemistry and Nanjing National Laboratory of Microstructure, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, PR China
Abstract:Bamboo-like carbon nanotubes (BCNTs) were synthesized via pyrolysis of PMMA@PDVB core-shell spheres in argon atmosphere at 900 °C without any metallic catalyst. TEM and HRTEM observations show the carbon nanotubes with bamboo-like structure. The content of polymerized divinylbenzene (PDVB) in the core-shell nanostructures plays a very important role for the formation of BCNTs. The possible growth mechanism for BCNTs is proposed.
Keywords:Microstructure   Nanomaterials   Carbon nanotubes   Bamboo-like structure   Non-catalytic   Pyrolysis
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