Synthesis and optically acid-sensory properties of novel polyoxadiazole derivatives |
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| Authors: | Nam Choul YangSeok Chang Dong Hack Suh |
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| Affiliation: | a School of Chemical Engineering, College of Engineering, Hanyang University, 17 Haengdang 1-dong, Seongdong-gu, Seoul 133-791, South Korea
b Samsung Advanced Institute of Technology, P.O. Box 111, Suwon 400-600, South Korea |
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| Abstract: | New organo-soluble and blue-emissive fluorene-based polyoxadiazoles, PFOx and PFOxEH, exhibit colorimetric and fluorescent acid-sensory properties to a strong acid due to the weak basicity of imine-type nitrogen atom(s) in an 1,3,4-oxadiazole ring. To further investigate their protonation with an acid, 1H NMR spectroscopy and AM1 semiempirical quantum-mechanics are utilized as well as UV-visible absorption and fluorescence spectroscopies. These investigations indicate the protonation does not proceed thermodynamically but kinetically at the initial stage of the complex formation of an acid and an oxadiazole ring in the polymer backbone. |
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| Keywords: | Polyoxadiazole Conjugated polymer sensor Fluorescence |
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