Dilute solution properties of hydrophobically associating polyacrylamide: fitted by different equations |
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| Authors: | Juntao Ma Bin LiangPing Cui Hua DaiRonghua Huang |
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| Affiliation: | The State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, Sichuan 610065, People's Republic of China |
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| Abstract: | In this paper six different equations were used to fit the data of dilute solution of both nonionic (PBAM3) and ionic (PBAMS) hydrophobically associating polyacrylamide with and without the addition of NaCl. The results showed that Fedors equation was the most accurate equation to describe the dilute solution properties of these kinds of polymers. The lower value of the polymer concentration parameter (Cm) in Fedors equation was corresponded to the higher value of the constant k in Schulz-Blaschke equation for PBAM3 system. Two types of polymers had anti-polyelectrolyte effect. In dilute solution the PBAMS polymer chains had a more extended conformation than those of PBAM3 due to the existence of ionic groups. |
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| Keywords: | Hydrophobically associating polyacrylamide Dilute solution Fedors equation |
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