Preparation and electrochemical performance of the novel porous cobalt-nickel-zinc oxides/carbon nanocomposites |
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Authors: | ZHANG Shuirong LIU Kaiyu YI Xiaoyi HE Fang XIE Qingliang |
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Affiliation: | College of Chemistry and Chemical Engineering,Central South University,Changsha 410083,Hunan,China |
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Abstract: | Metal-organic frameworks (MOF-5) as template and the sources of carbon and zinc, the cobalt-nickel-zinc oxides/carbon nanocomposites have been synthesized by impregnation method following by a calcinations procedure. The microstructure and morphology of Co-Ni-Zn oxides/C composite are characterized by XRD,SEM,EDS and nitrogen adsorption/desorption experiment. The result shows that the Co-Ni-Zn oxides/C composites display a porous structure with a specific surface area of 155 m2/g. The electrochemical performances are investigated by CV, galvanostatic charge-discharge tests and EIS. The specific capacitance of as-prepared porous Co-Ni-Zn oxides/C composites is 804 F/g at 1 A/g with the retention ratio of 94.4% after 1000 cycles, which is much higher than that of Co-Ni oxides (180 F/g). The high rate discharge (HRD) for porous Co-Ni-Zn oxides/C composites reaches to 90% at 10 A/g. |
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Keywords: | cobalt-nickel-zinc oxides/carbon composites MOF-5 template method supercapacitors |
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