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采用BaCO_3—Li_2CO_3作电极的固体电解质CO_2传感器
引用本文:孙良彦,平田光寿.采用BaCO_3—Li_2CO_3作电极的固体电解质CO_2传感器[J].传感器与微系统,1994(1):9-14.
作者姓名:孙良彦  平田光寿
作者单位:中国吉林大学 (孙良彦,洪军,王梅),日本千叶工业大学(平田光寿)
摘    要:采用NASICON(Na离子导体)与BaCO_3-Li_2CO_3电极相结合的方式,使新型CO_2传感器得到发展。据观察,其响应时间以及抗水湿性能都有了提高。对于CO_2浓度在1×10~(-4)~0.5这样宽的范围内,500℃时测得的电动势与能斯特方程符合的很好。该元件几乎不受共存的H_2S(10~(-4)),NO_2(10~(-4)),CO(10~(-4)),SO_2(10~(-4)),C_2H_5OH(10~(-4))、CH_4(5×10~(-3))以及NH_3(2×10~(-3))的影响。

关 键 词:NASICON  BaCO_3-Li_2CO_3电极  新型CO_2传感器  固体电解质

Solid Electrolyte CO_2 Sensor Using BaCO_3-Li_2CO_3 Carbonate Electrode
Sun Liangyan Hong Jun Wang Mei.Solid Electrolyte CO_2 Sensor Using BaCO_3-Li_2CO_3 Carbonate Electrode[J].Transducer and Microsystem Technology,1994(1):9-14.
Authors:Sun Liangyan Hong Jun Wang Mei
Abstract:New type CO2 sensor was developed by combining NASICON and BaCO3-Li2CO3 electrode. It was found to be greatly improved in response time and water vapor-resistance. For a wide of CO2 concentration from 10-4~0.5, the electromotive force examined at 500℃ followed a Nemst's equation excellently. The sensor EMF was hardly affected by the coexistence of H2S(10-4)、 NO2(10-4)、CO(10-4)、SO2(10-4)、C2H5OH(10-4),CH-4(5×10-3) and NH3 (2×10-3).
Keywords:NASICON BaCO_3-Li_2CO_3 electrode New type CO_2 sensor Solid electrolyte
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