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| 铅酸电池生产废弃物制备3BS、4BS和4BS-BaPbO3 | |
| 引用本文： | 吴战宇,雷立旭,顾立贞,董志成.铅酸电池生产废弃物制备3BS、4BS和4BS-BaPbO3[J].电池,2011,41(5):287-290. |
| 作者姓名： | 吴战宇 雷立旭 顾立贞 董志成 |
| 作者单位： | 1. 江苏华富控股集团,江苏扬州,225600 2. 东南大学化学化工学院,江苏南京,211106 3. 江苏华富储能新技术发展有限公司,江苏扬州 225600;江苏华富控股集团,江苏扬州225600 |
| 基金项目： | 江苏省重大科技成果江苏省科技成果转化专项资金 |
| 摘 要： | 以铅酸电池生产废弃物——废弃淋酸铅膏、分片废粉及报废极板铅膏等为原料,通过烧结法制备三碱式硫酸铅(3BS)、四碱式硫酸铅(4BS)及4BS-铅酸钡(BaPbO3)等3种添加剂,方法简便有效,产品纯度达94％以上,可直接用于铅膏生产.与普通铅酸电池相比,使用制备的3BS、4BS及4BS-BaPbO3添加剂的铅酸电池,容量... |
| 关 键 词： | 废弃物 烧结 三碱式硫酸铅(3BS) 四碱式硫酸铅(4BS) 铅酸钡(BaPbO3) |
Preparing 3BS, 4BS and 4BS-BaPbO3 with production scraps of Iead-acid battery |
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| WU Zhan-yu,LEI Li-xu,GU Li-zhen,DONG Zhi-cheng.Preparing 3BS, 4BS and 4BS-BaPbO3 with production scraps of Iead-acid battery[J].Battery Bimonthly,2011,41(5):287-290. | |
| Authors: | WU Zhan-yu LEI Li-xu GU Li-zhen DONG Zhi-cheng |
| Affiliation: | 1(1.Jiangsu Huafu Holding Group,Yangzhou,Jiangsu 225600,China;2.School of Chemistryand Chemical Engineering,Southeast University,Nanjing,Jiangsu 211106,China;3.Jiangsu HuafuStorage New Technology Development Co.,Ltd.,Yangzhou,Jiangsu 225600,China) |
| Abstract: | Tribasic lead sulphate(3BS),tetrabasic lead sulphate(4BS) and 4BS-barium lead oxide(BaPbO3) additives were prepared by the method of sintering with the scraps from the production of lead-acid battery involved the scrap lead paste,the reclaimed lead powder and the scrap pole plates.The method was simple and effective,all of the contents of additives were more than 94%,the additives could be used in the production of lead paste directly.Compared with common lead-acid battery,the capacity of lead-acid battery using prepared 3BS,4BS and 4BS-BaPbO3 additives was 98.4%,103.2% and 104.8%,respectively,the heavy load ability increased 0.5%,0.5% and 2.0%,respectively,the cycle life prolonged 54 cycles,50 cycles and 5 cycles,respectively. |
| Keywords: | scraps sintering tribasic lead sulphate(3BS) tetrabasic lead sulphate(4BS) barium lead oxide(BaPbO3) |
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