ZrO2-SiO2 AEROGEL SUPPORTED COBALT CATALYSTS FOR THE SYNTHESIS OF LONG-CHAIN HYDROCARBON FROM SYNGAS |
| |
Authors: | Yongqing Zhang Hongwei Xiang Bing Zhong Qin Wang |
| |
Affiliation: |
a State Key Laboratory of Coal Conversion, Institute of Coat Chemistry, Chinese Academy of Sciences, Taiyuan, P.R.China |
| |
Abstract: | The effect of support and preparation method on the texture, surface area, extent of reduction, H2 desorption and Fischer-Tropsch synthesis(FTS) reaction properties of ZrO2-SiO2 aerogel supported cobalt-based catalysts was investigated. The results indicate that under the conditions that favor the formation of long-chain hydrocarbons, cobalt catalyzed FTS reaction appears to be structure sensitive. Support effects significantly influence the catalytic behavior. Cobalt catalyst supported on zirconia-coated silica aerogel leads to heavy products from syngas, in which case C5+ yield could reach 150g/Nm3(CO+H2) under the optimal conditions (T=293K, P=2.0MPa, GHSV=500h-1); cobalt catalyst supported on ZrO2-SiO2 mixed aerogel, however, was shown to produce middle distillate and the yield of C5-C20 products for this catalyst is about 120g/NM3 (CO+H2) |
| |
Keywords: | |
本文献已被 InformaWorld 等数据库收录! |
|