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固体推进剂用异佛尔酮二异氰酸酯的生产技术
引用本文:张香文,米镇涛,王春艳.固体推进剂用异佛尔酮二异氰酸酯的生产技术[J].火炸药学报,2001,24(3):67-69.
作者姓名:张香文  米镇涛  王春艳
作者单位:天津大学化工学院,
摘    要:比较了异佛尔酮二异氰酸酯(IPDI)的生产方法和经济性,传统光气法收率高,但毒性大,非光气法特别是DMC法反应条件温和,环境污染小,虽比光气法生产成本增加了5.45%,但仍然具有广泛的工业化应用前景。

关 键 词:IPDI  固化剂  光气法  非光气法  生产方法  经济性  火箭推进剂  DMC  异佛尔酮二异氰酸酯
文章编号:1007-7812(2001)03-0067-03
修稿时间:2000年5月19日

Progress on the Production of Isophorone Diisocyanate
ZHANG Xiang-wen,MI Zhen-tao,WANG Chun-yan.Progress on the Production of Isophorone Diisocyanate[J].Chinese Journal of Explosives & Propellants,2001,24(3):67-69.
Authors:ZHANG Xiang-wen  MI Zhen-tao  WANG Chun-yan
Abstract:Isophorone diisocyanate is industrially prepared using phosgene with a high selectivity, but phosgene has a strong toxicity and a strict control is needed when handling this compound. Nonphosgenation methods, especially reaction between IPDA and DMC, are clean production processes with mild reacton condition as well as satisfactory conversion and selectivity. Results of the economic comparison indicate that the product value using nonphosgenation process is about 5.45% more expensive than with the conventional method. Nonphosgenation methods are benign to environment and so they are promising in the future.
Keywords:IPDI  Curing agent  Phosgenation method  Nonphosgenation method
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