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La2CoFeO6竹节状中空纳米纤维的制备及其光催化性能
引用本文:毕 军,吴艳波,赵恒彦,魏斌斌.La2CoFeO6竹节状中空纳米纤维的制备及其光催化性能[J].无机材料学报,2015,30(10):1031-1036.
作者姓名:毕 军  吴艳波  赵恒彦  魏斌斌
作者单位:(大连交通大学 环境与化学工程学院, 大连 116028)
基金项目:国家自然科学基金(21076028) National Natural Science Foundation of China (21076028)
摘    要:采用静电纺丝法制得La2CoFeO6竹节状中空纳米纤维光催化材料。La2CoFeO6纳米纤维具有稳定的一维结构, 由菱形晶型的La2CoFeO6纳米颗粒相互连接组成, 并存在明显的竹节状中空结构, 其比表面积可达98.7 m2/g。La2CoFeO6纳米纤维对自然光具有较高的利用率, 其禁带宽度为1.6 eV。在甲基橙溶液浓度为10 mg/L, pH为2, 催化剂用量为1.5 g/L条件下, 自然光光照2 h后, La2CoFeO6纳米纤维对甲基橙的降解率可达96.9%。

关 键 词:La2CoFeO6纳米纤维  静电纺丝  光催化  中空结构  自然光  
收稿时间:2015-03-24
修稿时间:2015-05-11

Preparation and Photocatalytic Properties of La2CoFeO6 Bamboo-like Hollow Nanofibers
BI Jun,WU Yan-Bo,ZHAO Heng-Yan,WEI Bin-Bin.Preparation and Photocatalytic Properties of La2CoFeO6 Bamboo-like Hollow Nanofibers[J].Journal of Inorganic Materials,2015,30(10):1031-1036.
Authors:BI Jun  WU Yan-Bo  ZHAO Heng-Yan  WEI Bin-Bin
Affiliation:(College of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian 116028, China)
Abstract:La2CoFeO6 bamboo-like hollow nanofibers photocatalytic material was successfully prepared by electrostatic spinning. La2CoFeO6 nanofibers, which were connected to each other by rhombic La2CoFeO6 nanoparticles, had stable one-dimensional structure and clear bamboo-like hollow structure. The specific surface area of as-prepared inorganic nanofibers reached 98.7 m2/g. La2CoFeO6 nanofibers had a high utilization for natural light and its band gap was 1.6 eV. When concentration of methyl orange was 10 mg/L with pH of 2 and the dosage of La2CoFeO6 nanofibers was 1.5 g/L, methyl orange was degraded by La2CoFeO6 nanofibers within 2 h under natural light at 96.9%.
Keywords:La2CoFeO6 nanofibers  electrostatic spinning  photocatalysis  hollow structure  natural light  
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