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Study on Preparation and Properties of La2O3/MC Nylon Nanocomposites
作者姓名:林轩  张平民  尹周谰  陈启元
作者单位:[1]College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China [2]Chemistry Department, Zhanjiang Normal College, Zhanfiang 524048, China
摘    要:MC nylon,monomer casting nylon,is a newtypeof engineering plastics,whichis synthesized by anion-ic polymerization with caprolactam as the major rawmaterial,under normal pressure,pouring directlyto amould preheatedto a certaintemperature.It has manyadvantages,such as low polymerized temperature,si mple technology,high crystallinity,low-cost,highequipment efficiency as well as good mechanical prop-erties,shock decrease but wear proof,corrosion-resis-ting,self-ubricant,chemicals-resisting,wide us…

关 键 词:La2O3  MC尼龙  纳米复合材料  聚合反应  稀土  机械性能
文章编号:1002-0721(2005)06-0680-05
收稿时间:2005-08-30
修稿时间:2005-11-01

Study on Preparation and Properties of La2O3/MC Nylon Nanocomposites
Lin Xuan,Zhang Pingmin,Yin Zhoulan,Chen Qiyuan.Study on Preparation and Properties of La2O3/MC Nylon Nanocomposites[J].Journal of Rare Earths,2005,23(6):680-684.
Authors:Lin Xuan  Zhang Pingmin  Yin Zhoulan  Chen Qiyuan
Abstract:A series of La2O3/MC nylon nanocomposites were prepared via in situ polymerization. The effects of content of nano-La2O3 on the mechanical properties of nanocomposites were studied. Dispersion of nano-La2O3 in MC nylon matrix was observed with SEM. The crystal structure of nanocomposites was characterized by means of XRD. SEM analysis shows that La2O3 nanoparticles are uniformly dispersed in MC nylon matrix and little clustering exists when the content of nano-La2O3 is lower than 1%, however, when the content of nano-La2O3 is more than 1%, it begins to cluster. XRD analysis indicats that nano-La2O3 does not change the crystal structure of MC nylon. Mechanical properties tests show that the tensile strength, elongation at break, impact strength, flexural strength, and flexural modulus of nanocomposites first increase then decrease as the content of nano-La2O3 is increased. When the content of nano-La2O3 is 0.5%, the tensile strength and elongation at break of nanocomposites reach maximum, which are 17.9% and 52.1% higher respectively than those of MC nylon. When the content of nano-La2O3 is 1.0%, the impact strength, flexural strength and flexural modulus of nanocomposites reach maximum, which are 36.6%, 12.7% and 16.3% higher respectively than those of MC nylon.
Keywords:MC nylon  nano-La2O3  nanocomposites  in situ polymerization  mechanical properties  rare earths
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