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Percolation model for brittle-tough transition in nylon/rubber blends
Authors:Alla Margolina  Souheng Wu  
Affiliation:

E. I. du Pont de Nemours and Company, Central Research and Development Department, Experimental Station, Wilmington, Delaware 19898, USA

Abstract:It is proposed that the brittle- tough transition in nylon/rubber blends occurs when the yielding process propagates through thin matrix ligaments in which a plane-strain to plane-stress transition takes place. This propagation process is modelled as a percolation phenomenon. The model explains the observed brittle-tough transition, and predicts that monodisperse and asymmetric particles are more effective in toughening than polydisperse and spherical ones.
Keywords:brittle-tough transition   percolation theory   polymer blends   impact strength   rubber toughening   nylon/rubber blends
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