E. I. du Pont de Nemours and Company, Central Research and Development Department, Experimental Station, Wilmington, Delaware 19898, USA
Abstract:
It is proposed that the brittle- tough transition in nylon/rubber blends occurs when the yielding process propagates through thin matrix ligaments in which a plane-strain to plane-stress transition takes place. This propagation process is modelled as a percolation phenomenon. The model explains the observed brittle-tough transition, and predicts that monodisperse and asymmetric particles are more effective in toughening than polydisperse and spherical ones.