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TiO2光催化氧化降解苯酚的研究
引用本文:李娜,李国德,郑治国,张阳,武士威,辛士刚,乔迎昕.TiO2光催化氧化降解苯酚的研究[J].精细石油化工进展,2010,11(10):38-40.
作者姓名:李娜  李国德  郑治国  张阳  武士威  辛士刚  乔迎昕
作者单位:[1]沈阳师范大学实验中心,沈阳110034 [2]沈阳师范大学教务处,沈阳110034 [3]沈阳师范大学化学与生命科学学院,沈阳110034 [4]北票市环境保护局,朝阳122100
基金项目:国家自然科学基金,省自然科学基金
摘    要:以TiO2为光催化剂,在紫外光照射下降解处理低浓度苯酚模拟废水,并以紫外一可见分光光度法作为分析手段,考察了TiO2光催化剂浓度对苯酚降解过程的影响。结果表明,当苯酚浓度为40mg/L时,TiO2光催化剂的最佳浓度为1.0g/L,此时苯酚去除率较高,达23.49%。同时对降解动力学的研究表明,苯酚的光催化降解过程符合一级反应动力学模式。

关 键 词:光催化  苯酚  二氧化钛  降解

Study on Photocatalytic Oxidative Degradation of Phenol by Titanium Dioxide
Li Na,Li Guode,Zheng Zhiguo,Zhang Yang,Wu Shiwei,Xin Shigang,Qiao Yingxin.Study on Photocatalytic Oxidative Degradation of Phenol by Titanium Dioxide[J].Advances in Fine Petrochemicals,2010,11(10):38-40.
Authors:Li Na  Li Guode  Zheng Zhiguo  Zhang Yang  Wu Shiwei  Xin Shigang  Qiao Yingxin
Affiliation:Li Na Li Guode Zheng Zhiguo Zhang Yang Wu Shiwei Xin Shigang Qiao Yingxin (1. Experimental Center of Shenyang Normal University, Shenyang 110034; 2. Office of Academic Affairs of Shenyang Normal University, Shenyang 110034 ; 3. Chemical and Life Science College of Shenyang Normal University, Shenyang 110034; 4. Environmental Protection Bureau of Beipiao , Chaoyang 122100)
Abstract:TiO2 was used as the photocatalyst for treating the simulated wastewater containing low concentration phenol through degradation under the irradiation of UV light, and UV - vis light spectrophotometry was adopted for studying the effect of the concentration of TiO2 photocatalyst on the degradation of phenol. The results have shown that the optimum concentration of TiO2 photocatalyst is 1.0 g/L when the concentration of phenol is 40mg/L, at which the removal rate of phenol is high and can reach 23.49%. The study on degradation kinetics has shown that the degradation of phenol by photocatalyst is in accordance with the first -order reaction dynamic model.
Keywords:photocatalysis  phenol  titanium dioxide  degradation
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