| 壬基酚聚氧乙烯醚磷酸酯的合成及其在金属切削液中的应用 |
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| 引用本文： | 安同艳,尹树花.壬基酚聚氧乙烯醚磷酸酯的合成及其在金属切削液中的应用[J].精细石油化工进展,2011,12(7):30-32. |
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| 作者姓名： | 安同艳 尹树花 |
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| 作者单位： | 天津泰伦特化学有限公司,天津,300400 |
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| 摘 要： | 通过壬基酚聚氧乙烯醚(NP-10)与五氧化二磷(P2O5)反应,制备了壬基酚聚氧乙烯醚磷酸酯.采用正交试验,得到最佳反应条件为:n(NP-10):n(P2O5):n(H2O)=2.4:1:1,反应温度75℃,反应时间5h.在此条件下,酯化率可达93%以上.将产物用于金属切削液配方中,加量3%时,10%切削液水溶液的最大...
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| 关 键 词： | 壬基酚聚氧乙烯醚磷酸酯 壬基酚聚氧乙烯醚 金属切削液 正交试验 |
Synthesis of Nonylphenol Polyoxyethylene Ether Phosphate Ester and Its Application in Metal Cutting Fluid |
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| An Tongyan,Yin Shuhua.Synthesis of Nonylphenol Polyoxyethylene Ether Phosphate Ester and Its Application in Metal Cutting Fluid[J].Advances in Fine Petrochemicals,2011,12(7):30-32. |
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| Authors: | An Tongyan Yin Shuhua |
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| Affiliation: | An Tongyan Yin Shuhua (Tianjin Talent Chemistry Co.Ltd.,Tianjin 300400) |
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| Abstract: | Nonylphenol polyoxyethylene ether phosphate ester was synthesized from nonylphenol polyoxyethylene ether （NP- 10） and phosphorus pentoxide. The optimum reaction conditions were obtained by orthogonal test, which were as follows： n （ NP - 10） ： n （ P2O5 ） ： n （ H2O ） = 2.4 ： 1 ： 1, reaction temperature 75 ℃, and reaction time 5 hours. The esterification rate was more than 93% under above conditions. The product was applied in metal cutting fluid and when the amount of the product 3%, the maximum nonseizure load of 10% cutting fluid aqueous solution increased to 212 N from 88 N and the corrosion inhibition property and other properties of 5% cutting fluid aqueous solution meet the national standards. |
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| Keywords: | nonylphenol polyoxyethylene ether phosphate ester nonylphenol polyoxyethylene ether metal cutting fluid orthogonal test |
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