| 齐格勒-纳塔催化剂催化癸烯聚合反应的研究 |
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| 引用本文： | 韩雪梅,王淑兰,曹婷婷,魏君凤,徐可忠,于部伟. 齐格勒-纳塔催化剂催化癸烯聚合反应的研究[J]. 精细石油化工进展, 2011, 12(9): 30-32 |
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| 作者姓名： | 韩雪梅 王淑兰 曹婷婷 魏君凤 徐可忠 于部伟 |
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| 作者单位： | 1. 大庆化工研究中心,大庆,163714
2. 中国石油天然气集团公司,北京,100027 |
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| 摘 要： | 用Ziegler - Natta(齐格勒—纳塔)催化剂对癸烯的聚合行为进行了研究.在聚合温度70℃、压力0.7 MPa,聚合时间3h条件下,探讨了齐格勒—纳塔催化剂类型、催化剂用量和助催化剂对催化性能的影响.结果表明,以TiCl4/SiO2/(C2 H5)1.5AlCl1.5为催化剂,在Al与Ti物质的量比为40时,癸...
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| 关 键 词： | 癸烯 齐格勒—纳塔催化剂 低聚 |
Study of Decene Oligomerization Catalyzed by Ziegler-Natta Catalyst |
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| Han Xuemei,Wang Shulan,Cao Tingting,Wei Junfeng,Xu Kezhong,Yu Buwei. Study of Decene Oligomerization Catalyzed by Ziegler-Natta Catalyst[J]. Advances in Fine Petrochemicals, 2011, 12(9): 30-32 |
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| Authors: | Han Xuemei Wang Shulan Cao Tingting Wei Junfeng Xu Kezhong Yu Buwei |
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| Affiliation: | Han Xuemei1 Wang Shulan1 Cao Tingting1 Wei Junfeng1 Xu Kezhong2 Yu Buwei1(1.Daqing Petrochemical Research Center,Daqing 163714,2.China National Petrochemical Corporation,Beijing 100027) |
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| Abstract: | The behaviors of decene oligomerization catalyzed by Ziegler - Natta catalyst were studied. Theeffects of the type of Ziegler - Natta catalyst, amount of the catalyst, and promoter on the catalysis were investigated under the conditions of temperature 70℃ pressure 0.7 MPa, and reaction time 3 hours. The results showed that the conversion rate of decene was up to 67% and the kinematic viscosity of the decene oligomer was 85 mm2/s at 100 ℃ using TiC4/SiO2（ C2H5）1.5AlCl1.5 as catalyst with molar ratio of Al to Ti 40. |
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| Keywords: | decene oligomerization Ziegler-Natta catalyst |
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