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FeNi doped porous carbon as an efficient catalyst for oxygen evolution reaction
作者姓名:Jun-Wei Zhang  Hang Zhang  Tie-Zhen Ren  Zhong-Yong Yuan  Teresa JBandosz
作者单位:Hebei Provincial Key Laboratory of Green Chemical Technology&High Efficient Energy Saving;Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education);Department of Chemistry and Biochemistry
基金项目:This work was supported by the National Natural Science Foundation of China(Grant Nos.21421001,21875118);the 111 Project(Grant No.B12015).
摘    要:Polymer-derived porous carbon was used as a support of iron and nickel species with an objective to obtain an efficient oxygen reduction reaction(OER)catalyst.The surface features were extensively characterized using X-ray diffraction,X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy.On FeNi-modified carbon the overpotential for OER was very low(280 mV)and comparable to that on noble metal catalyst IrO2.The electrochemical properties have been investigated to reveal the difference between the binary alloy-and single metal-doped carbons.This work demonstrates a significant step for the development of low-cost,environmentally-friendly and highly-efficient OER catalysts.

关 键 词:OER  polystyrene  salt  porous  carbon  FeNi  alloy  p/n  junction

FeNi doped porous carbon as an efficient catalyst for oxygen evolution reaction
Jun-Wei Zhang,Hang Zhang,Tie-Zhen Ren,Zhong-Yong Yuan,Teresa JBandosz.FeNi doped porous carbon as an efficient catalyst for oxygen evolution reaction[J].Frontiers of Chemical Science and Engineering,2021,15(2):279-287.
Authors:Jun-Wei Zhang  Hang Zhang  Tie-Zhen Ren  Zhong-Yong Yuan  Teresa J Bandosz
Affiliation:1. Hebei Provincial Key Laboratory of Green Chemical Technology & High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China2. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), School of Materials Science and Engineering, Nankai University, Tianjin 300350, China3. Department of Chemistry and Biochemistry, The City College of New York, New York, NY 10031, USA
Abstract:Polymer-derived porous carbon was used as a support of iron and nickel species with an objective to obtain an efficient oxygen reduction reaction (OER) catalyst. The surface features were extensively characterized using X-ray diffraction, X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy. On FeNi-modified carbon the overpotential for OER was very low (280 mV) and comparable to that on noble metal catalyst IrO2. The electrochemical properties have been investigated to reveal the difference between the binary alloy- and single metal-doped carbons. This work demonstrates a significant step for the development of low-cost, environmentally-friendly and highly-efficient OER catalysts.
Keywords:OER  polystyrene salt  porous carbon  FeNi alloy  p/n junction  
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