Controlled synthesis of crosslinked polyamide 6 using a bis-monomer derived from cyclized lysine |
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Authors: | Hassen Bouchékif Deniz Tunc Cédric Le Coz Alain Deffieux Philippe Desbois Stéphane Carlotti |
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Affiliation: | 1. Univ. Bordeaux, Laboratoire de Chimie des Polymères Organiques, UMR 5629, IPB/ENSCBP, 16 Avenue Pey-Berland, F-33607 Pessac Cedex, France;2. Centre National de la Recherche Scientifique, Laboratoire de Chimie des Polymères Organiques, UMR 5629, F-33607 Pessac Cedex, France;3. BASF SE, Advanced Material and System Research, D-67056 Ludwigshafen, Germany |
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Abstract: | The controlled synthesis of polyamide 6 chemical networks by anionic ring-opening copolymerization of ε-caprolactam (CL) with synthesized bis-ε-caprolactam derived from α-amino-ε-caprolactam, i.e. N-functionalized α-amino-ε-caprolactam bis-monomers, using sodium ε-caprolactamate as an initiator and hexamethylene-1,6-dicarbamoylcaprolactam as di-functional fast activator was examined in bulk at 140 °C. An urea-based bis-monomer and CL were first shown to copolymerize with a decreasing polymerization rate due to side reactions. On the contrary, quantitative copolymerization of CL with various amounts of bis-N(2-oxo-3-azepanyl)-1,6-tetramethylenediamide, an amide-based bis-monomer, leads to fast kinetics similar to the homopolymerization of CL. Crosslinked PA6 with network exhibiting elastic or viscoelastic behaviors, depending on the amount of crosslinker, were observed and characterized by swelling in hexafluoroisopropanol, dynamic mechanical analysis and rheology measurements. Crystallinity and swelling were shown to decrease with the increasing content of the crosslinking agent. |
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Keywords: | Anionic ring-opening polymerization ε-Caprolactam α-Amino-ε-caprolactam |
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