Functionalized graphenes with polymer toughener as novel interface modifier for property-tailored polylactic acid/graphene nanocomposites |
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Authors: | Yu Fu Linshu Liu Jinwen Zhang William C Hiscox |
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Affiliation: | 1. School of Mechanical and Materials Engineering & Composite Materials and Engineering Center, Washington State University, Pullman, WA 99164, United States;2. Eastern Regional Research Center, Agricultural Research Service, US. Department of Agriculture, 600 East Mermaid Lane, Wyndmoor, Pennsylvania 19038, United States;3. Nuclear Magnetic Resonance Center, Washington State University, Pullman, WA 99164, United States |
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Abstract: | In this work, an effective strategy for engineering the interfacial compatibility between graphene and polylactic acid (PLA) was developed by manipulating the functionalization of graphene and introducing an epoxy-containing elastomer modifier. Curing between the functional groups of the modified graphene and the epoxy groups of the elastomer modifier resulted in controlled dispersion and distribution of graphene in the composite system and hence improved the interfacial adhesion between PLA and graphene. Effects of different graphene functionalization with polymer toughener on morphology, viscoelasticity, and thermal properties of the resulting PLA nanocomposites were thoroughly examined. The resulting percolated structures were the origin of the improved properties of PLA/graphene nanocomposites. The mechanism on property tailoring from interface engineering through dual modifiers are also proposed. Overall, the insight into the interface engineering between the functionalized graphene and the matrix through an elastomer modifier offers a novel way for the future design of graphene polymer nanocomposites. |
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Keywords: | Functionalized graphene Interfacial modifier Polylactic acid nanocomposites |
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