Covalent modification of graphene oxide with polynorbornene by surface-initiated ring-opening metathesis polymerization |
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Authors: | Qiuping Zhang Qing-Lan LiShidong Xiang Yan WangChunyang Wang Wei JiangHang Zhou Ying-Wei Yang Jun Tang |
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Affiliation: | College of Chemistry, State Key Laboratory for Supramolecular Structure and Materials, Jilin University, Changchun, Jilin 130012, PR China |
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Abstract: | Surface-initiated ring-opening metathesis polymerization (SI-ROMP) was employed to prepare polymer-grafted graphene oxide (GO). Grubbs catalysts were immobilized onto GO surfaces followed by ROMP of norbornene from these active catalyst sites to result in polynorbornene (PNb)-functionalized GO (GO-PNb), whose structure and morphology were fully characterized by FTIR, Raman, NMR, XRD, TGA and SEM. The as-prepared hybrid material of GO-PNb is an intercalated layer structure with an improved solubility in organic solvents. Further epoxidation of double bonds along the PNb chains resulted in the epoxidized PNb-functionalized GO (GO-ePNb). The relatively low and irregular grafting ratio of PNb on GO measured by gravimetry mainly result from the effect of complex GO surfaces and the chain-transfer reactions in the polymerization process. |
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Keywords: | Graphene oxide Surface-initiated ring-opening metathesis polymerization Epoxidation |
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