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半预聚物法RIM聚氨酯弹性体的合成
引用本文:孔明涵,王庭慰,罗本喆,郁维铭. 半预聚物法RIM聚氨酯弹性体的合成[J]. 弹性体, 2007, 17(3): 23-26
作者姓名:孔明涵  王庭慰  罗本喆  郁维铭
作者单位:1. 南京工业大学,江苏,南京,210009
2. 南京东高科技股份有限公司,江苏,南京,211102
摘    要:采用半预聚物法合成了以L—MDI、DMTDA、PPO为原料的双组分RIM聚氨酯弹性体。研究了合成方法、扩链剂种类、硬段含量、异氰酸酯指数、催化剂用量、热处理时间、料温等因素对RIM聚氨酯弹性体性能的影响。结果表明,采用L—MDI/PPO/DMTDA半预聚物法制备的RIM聚氨酯弹性体具有良好的物理性能。

关 键 词:聚氨酯弹性体  半预聚物法  性能  微相分离
文章编号:1005-3174(2007)03-0023-04
收稿时间:2007-01-04
修稿时间:2007-01-04

Synthesis of RIM polyurethane elastomer by quasi-prepolymer method
KONG Ming-han,WANG Ting-wei,LUO Ben-zhe,YU Wei-ming. Synthesis of RIM polyurethane elastomer by quasi-prepolymer method[J]. China Elastomerics, 2007, 17(3): 23-26
Authors:KONG Ming-han  WANG Ting-wei  LUO Ben-zhe  YU Wei-ming
Affiliation:1. Nanjing University of Technology, Nanj ing 210009, China ; 2. Nanjing Donggao Technology Co. ,Ltd,Nanjing 211102,China
Abstract:The RIM polyurethane elastomer was prepared by means of quasi-prepolymer process, with L-MDI, DMTDA.PPO as materials. The key affecting factors, such as synthesis method, variety of chain extender, hard segment content, isocyanate index, catalyst concentration , postcuring time and temperatuare of row material,on mechanical properties of RIM elastomer were discussed. The result indicated that the RIM elastomer of L-MDI/PPO/DMTDA by quasi-propolymer process had good technological properties.
Keywords:RIM
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