Surface reconstructions on Sb-irradiated GaAs(0 0 1) formed by molecular beam epitaxy |
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Affiliation: | 1. Nanoelectronics Collaborative Research Center, The Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan;2. Department of Electronic Engineering, The University of Electro-Communications, 1-5-1 Chofugaoka, Chofu-shi, Tokyo 182-8585, Japan;3. Department of Applied Mathematics and Physics, Tottori University, Tottori 680-8552, Japan;4. Computational Astrophysics Laboratory, RIKEN, 2-1 Hirosaki, Wako, Saitama 351-0198, Japan |
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Abstract: | Reconstructed surfaces on Sb-irradiated GaAs(0 0 1) formed by molecular beam epitaxy have been studied by in-situ scanning tunneling microscopy (STM). The reflection high-energy electron diffraction patterns showed (2×3) or weak (4×3)] structure. The step density was about five times higher than that of GaAs(0 0 1)-c(4×4) surface. It was found that there were swinging dimer rows along to the 1 1¯ 0] direction, which seemed not to consist of a specified reconstruction. We proposed two (2×3)-structure models for these swinging dimers. By first-principles calculation, we found that the proposed models were stable and with energy difference was 0.17 eV, indicating the coexistence of the two structures. Moreover, we proposed three (4×3) reconstruction models based on these (2×3) models. The electron counting rule was applied for these models, indicating that there was an excessive amount of electrons. By two bias-alternative STM images, it was found that the many spots appear only in empty-state. These might be segregated Ga or Sb cluster and strongly relate to the excessive amount of electrons. |
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