| 三氮杂桥C60衍生物的合成及其非线性光学性质 |
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| 引用本文： | 李丽,梁宇,陈改荣,陈小莲,唐光诗.三氮杂桥C60衍生物的合成及其非线性光学性质[J].光电子．激光,2011(9):1371-1375. |
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| 作者姓名： | 李丽 梁宇 陈改荣 陈小莲 唐光诗 |
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| 作者单位： | 新乡学院化学与化工学院；;新乡学院化学与化工学院；;新乡学院化学与化工学院；;北京化工大学可控化学反应科学与技术教育部重点实验室；;北京化工大学可控化学反应科学与技术教育部重点实验室； |
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| 基金项目： | 河南省重点科技攻关项目(112102210433) |
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| 摘 要： | 制备和研究了三氮杂桥C60衍生物（C60TA）的非线性光学性质。利用紫外（UV-Vis）、质谱（MS）和核磁（NMR）对制备的C60TA进行结构表征,UV-Vis谱图450 nm波长处无明显线性吸收,是非常好的非线性光学化合物。利用Z-扫描实验测定了在波长为532 nm、脉宽为8 ns条件下C60TA的非线性性能,结果...
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| 关 键 词： | 非线性光学 表征 Z-扫描 光限幅 三氮杂桥C60衍生物(C60TA) |
Synthesis and nonlinear optical properties of triaza-bridged[60] fullerene derivate |
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| LI Li,LIANG Yu,CHEN Gai-rong,CHEN Xiao-lian and TANG Guang-shi.Synthesis and nonlinear optical properties of triaza-bridged[60] fullerene derivate[J].Journal of Optoelectronics·laser,2011(9):1371-1375. |
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| Authors: | LI Li LIANG Yu CHEN Gai-rong CHEN Xiao-lian and TANG Guang-shi |
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| Affiliation: | School of Chemistry and Chemical Engineering,Xinxiang University,Xinxiang 453003,China;;School of Chemistry and Chemical Engineering,Xinxiang University,Xinxiang 453003,China;;School of Chemistry and Chemical Engineering,Xinxiang University,Xinxiang 453003,China;;Key Laboratory of Science and Technology of Controllable Chemical Reactions,Education Ministry of China,Beijing University of Chemical Technology,Beijing 100029,China;Key Laboratory of Science and Technology of Controllable Chemical Reactions,Education Ministry of China,Beijing University of Chemical Technology,Beijing 100029,China |
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| Abstract: | The nonlinear optical properties of triaza-bridged fullerene derivative are reported.First,the structure was characterized by UV-vis,MS and NMR spectra.The compound has good nonlinear optical properties in UV-vis spectrum at 450 nm.Then the optical nonlinear property of this compound were measured using a Q-switched Nd:YAG laser with 8 ns pulse width at 532 nm.The reverse saturation absorption and nonlinear refraction were observed by means of Z-scan technique.The values of third-order optical n... |
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| Keywords: | nonlinear optics characterization Z-scan optical limiting triaza-bridged fullerene derivate(C60 TA) |
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