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ZnO量子点/SiO2复合器件的可调控电致发光研究
引用本文:宣荣卫,张晓松,牛喜平,徐建萍,吴燕宇,罗程远,李萍,吴金花,李岚.ZnO量子点/SiO2复合器件的可调控电致发光研究[J].光电子.激光,2011(11):1613-1616.
作者姓名:宣荣卫  张晓松  牛喜平  徐建萍  吴燕宇  罗程远  李萍  吴金花  李岚
作者单位:天津理工大学材料物理研究所;天津理工大学材料物理研究所;天津理工大学材料物理研究所;天津理工大学材料物理研究所;天津理工大学材料物理研究所;天津理工大学材料物理研究所;天津理工大学理学院;天津理工大学材料物理研究所;中国电子科技集团公司第五十四研究所;天津理工大学材料物理研究所
基金项目:国家自然科学基金资助项目(60877029,60977035,60907021和10904109);天津市自然科学基金资助项目(09JCYBJC01400和11JCYBJC00300);科技创新体系及条件平台建设计划资助项目(10SYSYJC28100)
摘    要:在不同浓度的SiO2乙醇溶液中制备了一系列ZnO量子点/SiO2复合材料,通过匀胶方法将其制备成复合薄膜器件。器件的电致发光(EL)随着SiO2浓度的增加逐渐蓝移。通过实验,探索了发生蓝移的机制。选取一种ZnO量子点/SiO2复合材料均匀混入不同质量的纯SiO2后,测试结果表明,该蓝移现象不是SiO2自身发光引起的。通...

关 键 词:ZnO量子点/SiO2复合材料  电致发光(EL)  光谱调控  量子尺寸效应

Investigation on tunable EL from ZnO QDs/SiO2 hybrid devices
XUAN Rong-wei,ZHANG Xiao-song,NIU Xi-ping,XU Jian-ping,WU Yan-yu,LUO Cheng-yuan,LI Ping,WU Jin-hua and LI Lan.Investigation on tunable EL from ZnO QDs/SiO2 hybrid devices[J].Journal of Optoelectronics·laser,2011(11):1613-1616.
Authors:XUAN Rong-wei  ZHANG Xiao-song  NIU Xi-ping  XU Jian-ping  WU Yan-yu  LUO Cheng-yuan  LI Ping  WU Jin-hua and LI Lan
Affiliation:College of Science,Tianjin University of Technology,Tianjin 300384,China;Key Laboratory of Display Materials and Photoelectric Devices,Ministry of Education of China,Institute of Material Physics,Tianjin University of Technology,Tianjin 300384,China;Key Laboratory of Display Materials and Photoelectric Devices,Ministry of Education of China,Institute of Material Physics,Tianjin University of Technology,Tianjin 300384,China;Key Laboratory of Display Materials and Photoelectric Devices,Ministry of Education of China,Institute of Material Physics,Tianjin University of Technology,Tianjin 300384,China;Key Laboratory of Display Materials and Photoelectric Devices,Ministry of Education of China,Institute of Material Physics,Tianjin University of Technology,Tianjin 300384,China;Key Laboratory of Display Materials and Photoelectric Devices,Ministry of Education of China,Institute of Material Physics,Tianjin University of Technology,Tianjin 300384,China;Key Laboratory of Display Materials and Photoelectric Devices,Ministry of Education of China,Institute of Material Physics,Tianjin University of Technology,Tianjin 300384,China;College of Science,Tianjin University of Technology,Tianjin 300384,China;Key Laboratory of Display Materials and Photoelectric Devices,Ministry of Education of China,Institute of Material Physics,Tianjin University of Technology,Tianjin 300384,China;The 54th Research Institute,Electronics Technology Group Corporation of China,Shijiazhuang 050200,China);Key Laboratory of Display Materials and Photoelectric Devices,Ministry of Education of China,Institute of Material Physics,Tianjin University of Technology,Tianjin 300384,China
Abstract:The ZnO QDs/SiO2 composite materials,which were synthesized in different concentrations of SiO2-ethanol solution,were fabricated into light-emitting devices by spin coating.With the increase of SiO2 concentration,electroluminescence(EL) spectra of the devices are blue shift gradually.Experiments were designed and carried out to explore the mechanism of the spectrum-tunable EL with SiO2.The EL spectra of the series of devices,which were fabricated with the mixtures of the ZnO QDs/SiO2 sample and pure SiO2 in different molar ratios,indicate that the spectrum-tunable EL performance is not related to the emission of SiO2.The quantum size effect may be significant for the spectrum-tunable EL behavior,Gaussian multi-peak fitting for EL spectra showed that the increased ratio of green and orange-red emission with the increasing SiO2 concentration results in the blue shift of EL spectra.
Keywords:ZnO QDs/SiO2 composite material  electroluminescence(EL)  tunable spectrum  quantum size effects
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